Measuring Electrode Kinetics Under Spatial Confinement. Application of Pulse Voltammetry to Different Mass Transport Modes Using Butler–Volmer and Marcus–Hush–Chidsey Frameworks
José V. Hernández-Tovar, Antonio J. Martínez-García, Francisco Martínez-Ortiz, Eduardo Laborda, Manuela López-Tenés, Joaquín González · 2026
Read Measuring Electrode Kinetics Under Spatial Confinement. Application of Pulse Voltammetry to Different Mass Transport Modes Using Butler–Volmer and Marcus–Hush–Chidsey Frameworks by José V. Hernández-Tovar, Antonio J. Martínez-García, Francisco Martínez-Ortiz, Eduardo Laborda, Manuela López-Tenés, Joaquín González (2026) in the Tower of Babel, a free online library of public-domain works preserved in clean, searchable text. No sign-up. The full text is served as a plain-text file at a predictable URL, where text is present: https://antarctic-labs.com/tower-of-babel/pmc-13495712.txt.
Description
José V. Hernández-Tovar and others develop theory and tests for probe rates under tight spacing, where liquid layers are thinner than the spread layer. In 2026, the work covers films, porous probes, and redox cycling devices, where standard open-ended spread methods fail. Two mass transport modes are treated: drain of live species and charge rebirth.
Pulse voltage scans are put forward as a simple, exact method for slow rates, with telling current-voltage marks that reveal key settings. Applied to rusting of a TEMPO radical on a boron-doped diamond probe, the Marcus-Hush-Chidsey rules fit both transport modes more cleanly than Butler-Volmer. Probe chemists gain tools fitted to tight systems.
Catalog record
| CREATOR | José V. Hernández-Tovar, Antonio J. Martínez-García, Francisco Martínez-Ortiz, Eduardo Laborda, Manuela López-Tenés, Joaquín González |
|---|---|
| YEAR | 2026 |
| COLLECTION | PAPERS |
| FORMAT | TXT |
| FILE SIZE | 56 KB |
| VERSION | 1.0 |
| LICENSE | CC BY 4.0 |
| RIGHTS | CC BY |
| SOURCE | Europe PMC |