A KO2‑Based Solid Superoxide Reservoir for Irreversible Capacity Compensation in Superoxide-Based Na–O2 Batteries

Cuiyi Deng, Yu Zhong, Lei Qin, Yiying Wu · 2026

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Description

Deng, Zhong, Qin, and Wu tackle a fading problem in sodium-oxygen batteries in this 2026 study. These batteries promise cheap, high-capacity storage, but side reactions steadily consume their active superoxide, a reactive oxygen compound, so each recharge recovers less capacity than the last. The team added a solid reservoir of potassium superoxide, a commercial chemical, to replace what is lost.

Tests and spectroscopy showed the reservoir did two jobs. It directly supplied extra superoxide to cover early losses. It also helped the battery form its own sodium superoxide more effectively. Cells built this way averaged a Coulombic efficiency of 98.5 percent, meaning nearly all charge put in came back out during discharge. They also kept cycling for more than 600 rounds, far longer than untreated versions.

Catalog record

CREATORCuiyi Deng, Yu Zhong, Lei Qin, Yiying Wu
YEAR2026
COLLECTIONPAPERS
FORMATTXT
FILE SIZE27 KB
LICENSEhttps://creativecommons.org/licenses/by/4.0
RIGHTSCC BY
SOURCEEurope PMC

Source: https://europepmc.org/article/MED/PMC13474932

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