Controlling Photophysical Properties in Bis-Cyclometalated Ir(III)-Terpyridine Complexes through Photoinduced Intraligand Charge Transfer
Joanna Palion-Gazda, Aleksandra Kwiecień, Mateusz Penkala, Anna Kryczka, Barbara Machura, Patrycja Rawicka, Mariola Siwy, Dorota Kowalska, Sebastian Maćkowski, Ewa Schab-Balcerzak, Karol Erfurt · 2026
Read Controlling Photophysical Properties in Bis-Cyclometalated Ir(III)-Terpyridine Complexes through Photoinduced Intraligand Charge Transfer by Joanna Palion-Gazda, Aleksandra Kwiecień, Mateusz Penkala, Anna Kryczka, Barbara Machura, Patrycja Rawicka, Mariola Siwy, Dorota Kowalska, Sebastian Maćkowski, Ewa Schab-Balcerzak, Karol Erfurt (2026) in the Tower of Babel, a free online library of public-domain works preserved in clean, searchable text. No sign-up. The full text is served as a plain-text file at a predictable URL, where text is present: https://antarctic-labs.com/tower-of-babel/PMC13321313.txt.
Description
Joanna Palion-Gazda and co-authors tune light emitting iridium complexes in a 2026 chemistry study. The complexes pair iridium with terpyridine and benzothiazole based ligands and are candidates for light emitting devices. The team asked how a remote amine group on one ligand reshapes light output and device behaviour.
Plain model complexes glowed from a ligand centred excited state with sharp structure and little solvent shift. Adding the amine group smoothed the glow band and made it sensitive to solvent, signalling a switch to a mixed charge transfer state. Swapping in a triphenylamine group also steadied test devices built with the complexes. Wide lab methods, from voltage scans to light spectra, backed the assignments.
Catalog record
| CREATOR | Joanna Palion-Gazda, Aleksandra Kwiecień, Mateusz Penkala, Anna Kryczka, Barbara Machura, Patrycja Rawicka, Mariola Siwy, Dorota Kowalska, Sebastian Maćkowski, Ewa Schab-Balcerzak, Karol Erfurt |
|---|---|
| YEAR | 2026 |
| COLLECTION | PAPERS |
| FORMAT | TXT |
| FILE SIZE | 65111 |
| LICENSE | https://creativecommons.org/licenses/by/4.0 |
| RIGHTS | CC BY |
| SOURCE | Europe PMC |