Quinoid-controlled bond-length alternation enables high-mobility non-fused π-conjugated polymers

Tsubasa Mikie, Keitaro Iguchi, Ryosuke Kamimura, Kenta Tanaka, Hiroyuki Ishii, Itaru Osaka · 2026

Read Quinoid-controlled bond-length alternation enables high-mobility non-fused π-conjugated polymers by Tsubasa Mikie, Keitaro Iguchi, Ryosuke Kamimura, Kenta Tanaka, Hiroyuki Ishii, Itaru Osaka (2026) in the Tower of Babel, a free online library of public-domain works preserved in clean, searchable text. No sign-up. The full text is served as a plain-text file at a predictable URL, where text is present: https://antarctic-labs.com/tower-of-babel/PMC13250828.txt.

Description

Tsubasa Mikie and co-authors report a design shortcut for plastic electronics in this 2026 chemistry paper. Polymers that carry electric charge well usually need fused rings locked into the backbone, but this team reached high performance without any fused rings.

They tuned a feature called quinoid character, which controls how bond lengths alternate along the chain, by varying one building block's length. Stronger quinoid character evened out the bonds and let charge flow more freely along each chain. Test transistors carried both charge types at high speeds despite modest crystal order. The authors propose bond pattern tuning as a fresh design lever for organic electronics.

Catalog record

CREATORTsubasa Mikie, Keitaro Iguchi, Ryosuke Kamimura, Kenta Tanaka, Hiroyuki Ishii, Itaru Osaka
YEAR2026
COLLECTIONPAPERS
FORMATTXT
FILE SIZE22918
LICENSEhttps://creativecommons.org/licenses/by/4.0
RIGHTSCC BY
SOURCEEurope PMC

Source: https://europepmc.org/article/MED/PMC13250828

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