Structure making and breaking in electrolyte solutions explained by water energetics

Lucia F. Sedano, Luis Carlos Pardo, Gustavo Madrigal, Eva G. Noya, Carlos Vega · 2026

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Description

A peer-reviewed research article from Europe PMC (2026). SignificanceA prevailing dogma categorizes salts as structure-makers or structure-breakers to explain transport properties, but this classification lacks a clear molecular origin. Hydrogen bonds (HBs) are lost in the first hydration shell of ions but remain unaltered beyond it. The water–water energy is destabilized due to both HB loss and the disruption of dipole–dipole correlations imposed by the electric field of ions.

Catalog record

CREATORLucia F. Sedano, Luis Carlos Pardo, Gustavo Madrigal, Eva G. Noya, Carlos Vega
YEAR2026
COLLECTIONPAPERS
FORMATTXT
FILE SIZE45 KB
VERSION1.0
LICENSECC BY 4.0
RIGHTSCC BY
SOURCEEurope PMC

Source: https://europepmc.org/articles/PMC13099553

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