Revealing Progressive Degradation of Cobalt Oxide Nanoparticles During Thermochemical Redox Cycling via Operando STEM-EELS

Madeline Van Winkle, Stephen D. House, Yuxiang Peng, Yu-chen Karen Chen-Wiegart, Katherine Jungjohann, John S. Mangum · 2025

Read Revealing Progressive Degradation of Cobalt Oxide Nanoparticles During Thermochemical Redox Cycling via Operando STEM-EELS by Madeline Van Winkle, Stephen D. House, Yuxiang Peng, Yu-chen Karen Chen-Wiegart, Katherine Jungjohann, John S. Mangum (2025) in the Tower of Babel, a free online library of public-domain works preserved in clean, searchable text. No sign-up. The full text is served as a plain-text file at a predictable URL, where text is present: https://antarctic-labs.com/tower-of-babel/pmc-12766727.txt.

Description

Madeline Van Winkle, Stephen House, Yuxiang Peng, and a wider team wrote this research paper, published in 2025. It watches cobalt oxide particles break down as they are cycled through the heat-driven chemical reactions used to store energy.

Metal oxides are strong candidates for storing heat over long periods, but most tests look at bulk material. The team used an electron microscope that can heat samples and read their chemistry at the same time. They found the particles reacted much more slowly after the first cycle, because heat fused them into denser clumps. Humid air shifted the temperatures at which reactions switched, but did not stop the clumping. The authors say lasting gains must come from how the particles are made or shaped.

Catalog record

CREATORMadeline Van Winkle, Stephen D. House, Yuxiang Peng, Yu-chen Karen Chen-Wiegart, Katherine Jungjohann, John S. Mangum
YEAR2025
COLLECTIONPAPERS
FORMATTXT
FILE SIZE26 KB
VERSION1.0
LICENSECC BY 4.0
RIGHTSCC BY
SOURCEEurope PMC

Source: https://europepmc.org/articles/PMC12766727

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