Direct imaging of facet development during growth of single-crystal covalent organic frameworks

Qianxi Wang, Quan Wu, Yi He · 2025

Read Direct imaging of facet development during growth of single-crystal covalent organic frameworks by Qianxi Wang, Quan Wu, Yi He (2025) in the Tower of Babel, a free online library of public-domain works preserved in clean, searchable text. No sign-up. The full text is served as a plain-text file at a predictable URL, where text is present: https://antarctic-labs.com/tower-of-babel/pmc-12693983.txt.

Description

Qianxi Wang, Quan Wu, and Yi He filmed in 2025 how the faces of a single crystal grow, frame by frame. Their subject was COF-300, a covalent organic framework whose crystals promise fine order and strong performance. A dark-field microscope watched seeds grow live. The share of one linker, terephthalaldehyde, in the mix proved to steer both seed shape and which faces grew.

Low and high linker levels sent growth down unlike paths, one ruled by speed and one by stability, yielding unlike crystal shapes. Shape then set how much a crystal flexed after soaking up solvent. The team ties face change to linker dose and offers shape rules for future crystal design.

Catalog record

CREATORQianxi Wang, Quan Wu, Yi He
YEAR2025
COLLECTIONPAPERS
FORMATTXT
FILE SIZE26 KB
VERSION1.0
LICENSECC BY 4.0
RIGHTSCC BY
SOURCEEurope PMC

Source: https://europepmc.org/articles/PMC12693983

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