Oxidative coupling of N-nitrosoanilines with substituted allyl alcohols under rhodium (III) catalysis
Priyanka Chaudhary · 2024
Read Oxidative coupling of N-nitrosoanilines with substituted allyl alcohols under rhodium (III) catalysis by Priyanka Chaudhary (2024) in the Tower of Babel, a free online library of public-domain works preserved in clean, searchable text. No sign-up. The full text is served as a plain-text file at a predictable URL, where text is present: https://antarctic-labs.com/tower-of-babel/pmc-11685039.txt.
Description
Priyanka Chaudhary, writing alone in 2024, reported a rhodium-catalyzed method that joins two building blocks to make aldehydes and ketones with a nitroso group attached. The method activates a carbon-hydrogen bond on one partner and reacts it with allyl alcohols. It needs only a small amount of catalyst, tolerates many other groups, and reacts more strongly than past routes. A one-pot version that first makes the starting material also worked, as did two simpler partners that gave the same product.
Catalog record
| CREATOR | Priyanka Chaudhary |
|---|---|
| YEAR | 2024 |
| COLLECTION | PAPERS |
| FORMAT | TXT |
| FILE SIZE | 17 KB |
| VERSION | 1.0 |
| LICENSE | CC BY 4.0 |
| RIGHTS | CC BY |
| SOURCE | Europe PMC |