Atomic-Scale Imaging of Polymers and Precision Molecular Weight Analysis

Arkadios Marathianos, Alexandros Magiakos, Yisong Han, Ana Sanchez, Richard Whitfield, Jochen Kammerer, Athina Anastasaki, Paul Wilson, Joseph P Patterson, Christopher Barner-Kowollik, Evelina Liarou · 2024

Read Atomic-Scale Imaging of Polymers and Precision Molecular Weight Analysis by Arkadios Marathianos, Alexandros Magiakos, Yisong Han, Ana Sanchez, Richard Whitfield, Jochen Kammerer, Athina Anastasaki, Paul Wilson, Joseph P Patterson, Christopher Barner-Kowollik, Evelina Liarou (2024) in the Tower of Babel, a free online library of public-domain works preserved in clean, searchable text. No sign-up. The full text is served as a plain-text file at a predictable URL, where text is present: https://antarctic-labs.com/tower-of-babel/pmc-11664914.txt.

Description

Arkadios Marathianos and ten co-authors image single polymer chains at near-atomic sharpness and weigh them by counting their heavy atoms. Their paper appeared in two thousand twenty-four. Knowing a polymer's molecular weight precisely is basic to designing it. Yet seeing one chain clearly enough to count its parts was out of reach.

The trick is to build chains with metal-rich side groups that shine in an electron microscope. Dark-field scanning images then reveal each heavy atom along the chain. Counting atoms gives the weight directly, even at very low sample amounts. A common plain polymer was chemically tagged to join the club. That extends the method toward everyday plastics. The work opens polymer analysis at the level of single molecules.

Catalog record

CREATORArkadios Marathianos, Alexandros Magiakos, Yisong Han, Ana Sanchez, Richard Whitfield, Jochen Kammerer, Athina Anastasaki, Paul Wilson, Joseph P Patterson, Christopher Barner-Kowollik, Evelina Liarou
YEAR2024
COLLECTIONPAPERS
FORMATTXT
FILE SIZE17 KB
VERSION1.0
LICENSECC BY 4.0
RIGHTSCC BY
SOURCEEurope PMC

Source: https://europepmc.org/articles/PMC11664914

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