Enhanced Mn(II)/peracetic acid by nitrilotriacetic acid to degrade organic contaminants: Role of Mn(V) and organic radicals

Yiqing Liu, Runyu Zhou, Yuqi Tang, Xin Li, Linghan Xu, Yongsheng Fu · 2024

Read Enhanced Mn(II)/peracetic acid by nitrilotriacetic acid to degrade organic contaminants: Role of Mn(V) and organic radicals by Yiqing Liu, Runyu Zhou, Yuqi Tang, Xin Li, Linghan Xu, Yongsheng Fu (2024) in the Tower of Babel, a free online library of public-domain works preserved in clean, searchable text. No sign-up. The full text is served as a plain-text file at a predictable URL, where text is present: https://antarctic-labs.com/tower-of-babel/pmc-11607386.txt.

Description

Yiqing Liu and five co-authors report a cleaner way to break down a common drug pollutant in water, in this 2024 paper. The drug is sulfamethoxazole, and the base method pairs a manganese salt with peracetic acid to attack it. The team added a compound called NTA and found the cleanup sped up sharply.

Tests with light spectra, scavenger trials, and probe chemicals showed what does the work. The additive first binds the manganese, which then activates the acid and forms a high-energy manganese state plus organic radicals. That state proved to be the main attacker. The group traced six breakdown products and mapped four routes the drug can take apart, noting the process works in acidic and neutral water.

Catalog record

CREATORYiqing Liu, Runyu Zhou, Yuqi Tang, Xin Li, Linghan Xu, Yongsheng Fu
YEAR2024
COLLECTIONPAPERS
FORMATTXT
FILE SIZE26 KB
VERSION1.0
LICENSECC BY 4.0
RIGHTSCC BY
SOURCEEurope PMC

Source: https://europepmc.org/articles/PMC11607386

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