10-Valence-Electron C≡O and the 14-VE C≡Pt: Two Triple-Bonded Isoelectronic Families Differing by a dδ4 Ring
Michiko Atsumi, Pekka Pyykkö · 2023
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Description
Michiko Atsumi and Pekka Pyykkö compare, in 2023 work, two kin families of triple-bonded atom pairs. One family, with ten outer charges, holds famed pairs like nitrogen gas and carbon monoxide, each with a strong triple bond and a lone pair at each end. The other, with fourteen, swaps one end for a heavy metal.
The metal pairs keep the same bond core, the team finds, plus a flat ring of four charges in a side band of the metal. That ring leaves a mark in a field trait that labs can read, and sums with two math recipes track the read trends well. Chains and trios built on the pairs are also traced. The work gives a shared map for both families.
Catalog record
| CREATOR | Michiko Atsumi, Pekka Pyykkö |
|---|---|
| YEAR | 2023 |
| COLLECTION | PAPERS |
| FORMAT | TXT |
| FILE SIZE | 20 KB |
| VERSION | 1.0 |
| LICENSE | CC BY 4.0 |
| RIGHTS | CC BY |
| SOURCE | Europe PMC |