Noncovalent Grafting of Molecular Complexes to Solid Supports by Counterion Confinement

Petrus · 2023

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Description

Petrus Laan and co-authors present a noncovalent grafting method for molecular complexes on solid supports in a 2023 paper, credited in the hosted head under a short author tag. Pinning molecules to solids is a handy route to advanced materials.

The method rests on trapping counterions inside tiny pores on neutral surfaces. Three platinum complexes of very different size and charge were grafted the same way. Fine imaging showed even spread of complexes and counterions. Gas uptake tests confirmed pores held the counterions. Adsorption ran in two steps, fast surface sticking then slow migration into pore binding. Chemists get a simple, general route that avoids covalent links.

Catalog record

CREATORPetrus
YEAR2023
COLLECTIONPAPERS
FORMATTXT
FILE SIZE28 KB
VERSION1.0
LICENSECC BY 4.0
RIGHTSCC BY
SOURCEEurope PMC

Source: https://europepmc.org/articles/PMC10749480

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