Influence of ZSM-5 Crystal Size on Methanol-to-Olefin (MTO) vs. Ethanol-to-Aromatics (ETA) Conversion

Daniel Dittmann, Elif Kaya, Dennis Strassheim, Michael Dyballa, Jarosław Serafin, Beata Michalkiewicz · 2023

Read Influence of ZSM-5 Crystal Size on Methanol-to-Olefin (MTO) vs. Ethanol-to-Aromatics (ETA) Conversion by Daniel Dittmann, Elif Kaya, Dennis Strassheim, Michael Dyballa, Jarosław Serafin, Beata Michalkiewicz (2023) in the Tower of Babel, a free online library of public-domain works preserved in clean, searchable text. No sign-up. The full text is served as a plain-text file at a predictable URL, where text is present: https://antarctic-labs.com/tower-of-babel/pmc-10745704.txt.

Description

Daniel Dittmann and co-authors test how crystal size in the zeolite ZSM-5 changes two alcohol conversion processes. Zeolites serve as catalysts, and crystal size is one of their key traits. The crystals here were made alike in chemistry and acid traits, with few defects, so size alone could be judged.

Their 2023 study runs methanol-to-olefin and ethanol-to-aromatics conversion over crystals of varied size. Methanol gave short olefins, while ethanol gave larger olefins and aromatics. Bigger crystals shortened catalyst life in both feeds. Size shifted the product mix for methanol but not for ethanol, where fast coking left only the outer layers active. The split proves the two alcohols convert by apart mechanisms.

Catalog record

CREATORDaniel Dittmann, Elif Kaya, Dennis Strassheim, Michael Dyballa, Jarosław Serafin, Beata Michalkiewicz
YEAR2023
COLLECTIONPAPERS
FORMATTXT
FILE SIZE36 KB
VERSION1.0
LICENSECC BY 4.0
RIGHTSCC BY
SOURCEEurope PMC

Source: https://europepmc.org/articles/PMC10745704

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