Cyclometalated (N,C) Au(III) Complexes: The Impact of Trans Effects on Their Synthesis, Structure, and Reactivity
Marte Sofie Martinsen Holmsen, Ainara Nova, Mats Tilset · 2023
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Description
Marte Sofie Martinsen Holmsen, Ainara Nova, and Mats Tilset review a decade of work on a class of gold compounds in a 2023 paper. The compounds pair gold with a two-grip arm, and what sits across from each grip steers what the gold does. One term covers how a grip loosens the bond across from it at rest, and a wider term adds the speed-up during change.
The team shows how these cross effects pick the winners in adding carbon groups or swapping parts. Strong cross grips end up across from the arm's weaker end, by a clear rule. That rule lets chemists build made-to-order gold compounds on purpose.
Catalog record
| CREATOR | Marte Sofie Martinsen Holmsen, Ainara Nova, Mats Tilset |
|---|---|
| YEAR | 2023 |
| COLLECTION | PAPERS |
| FORMAT | TXT |
| FILE SIZE | 40 KB |
| VERSION | 1.0 |
| LICENSE | CC BY 4.0 |
| RIGHTS | CC BY |
| SOURCE | Europe PMC |