TMSCF3-Mediated Conversion of Salicylates into α,α-Difluoro-3-coumaranones: Chain Kinetics, Anion-Speciation, and Mechanism
Hannah · 2023
Read TMSCF3-Mediated Conversion of Salicylates into α,α-Difluoro-3-coumaranones: Chain Kinetics, Anion-Speciation, and Mechanism by Hannah (2023) in the Tower of Babel, a free online library of public-domain works preserved in clean, searchable text. No sign-up. The full text is served as a plain-text file at a predictable URL, where text is present: https://antarctic-labs.com/tower-of-babel/pmc-10729029.txt.
Description
Two chemists, Minshull and Lloyd-Jones, trace how a known lab reaction unfolds in a 2023 study. The reaction turns a common class of starting goods into ring-shaped goods with two fluorine atoms set in place. Past work had shown the change but not its full path.
The team watched the mix with fine probes as it ran, trapped fleeting parts, and raced close kin of the start goods side by side. They found five clear stages, each ruled by which charged bits held sway in the mix. Their speed model fits the first three stages and yields tips for lab use. Bench chemists gain a map of a fickle chain that can now be steered.
Catalog record
| CREATOR | Hannah |
|---|---|
| YEAR | 2023 |
| COLLECTION | PAPERS |
| FORMAT | TXT |
| FILE SIZE | 38 KB |
| VERSION | 1.0 |
| LICENSE | CC BY 4.0 |
| RIGHTS | CC BY |
| SOURCE | Europe PMC |